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Portal:Chemistry

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Introduction

Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during reactions with other substances. Chemistry also addresses the nature of chemical bonds in chemical compounds.

In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both basic and applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties of the soil on the Moon (cosmochemistry), how medications work (pharmacology), and how to collect DNA evidence at a crime scene (forensics).

Chemistry has existed under various names since ancient times. It has evolved, and now chemistry encompasses various areas of specialisation, or subdisciplines, that continue to increase in number and interrelate to create further interdisciplinary fields of study. The applications of various fields of chemistry are used frequently for economic purposes in the chemical industry. (Full article...)

Selected article

Ribbon diagram of phenylalanine hydroxylase, an enzyme which catalyses the reaction causing the addition of an hydroxyl group to the end of the 6-carbon aromatic ring of phenylalanine, such that it becomes tyrosine.
Enzymes are proteins that accelerate, or catalyze, chemical reactions. In these reactions, the molecules at the beginning of the process are called substrates, and the enzyme converts these into different molecules, the products. Almost all processes in the cell need enzymes in order to occur at significant rates. Since enzymes are extremely selective for their substrates and speed up only a few reactions from among many possibilities, the set of enzymes made in a cell determines which metabolic pathways occur in that cell.

Enzymes are known to catalyze about 4,000 reactions. However, not all biological catalysts are proteins, since some RNA molecules called ribozymes can also catalyze reactions. Enzymes are usually named according to the reaction they catalyze. Typically the suffix -ase is added to the name of the substrate (e.g., lactase is the enzyme that cleaves lactose) or the type of reaction (e.g., DNA polymerase forms DNA polymers).

Like all catalysts, enzymes work by providing an alternative path of lower activation energy for a reaction and dramatically accelerating its rate. Some enzymes can make their conversion of substrate to product occur many millions of times faster. For example, the reaction catalysed by orotidine 5'-phosphate decarboxylase will consume half of its substrate in 78 million years if no enzyme is present. However, when the decarboxylase is added, the same process takes just 25 milliseconds. Chemically, enzymes are like any catalyst and are not consumed in chemical reactions, nor do they alter the equilibrium of a reaction. However, enzymes do differ from most other catalysts by being much more specific.

Enzyme activity can be affected by other molecules. Inhibitors are molecules that decrease enzyme activity, and activators are molecules that increase activity. Drugs and poisons are often enzyme inhibitors.

Some enzymes are used commercially, for example, in the synthesis of antibiotics. In addition, some household cleaning products use enzymes to speed up chemical reactions (e.g., enzymes in biological washing powders break down protein or fat stains on clothes).

Subcategories

History and Philosophy of Chemistry

Antoine Lavoisier
Antoine Lavoisier

Many chemists have an interest in the history of chemistry. Those with philosophical interests will be interested that the philosophy of chemistry has quite recently developed along a path somewhat different from the general philosophy of science.

Other articles that might interest you are:

There is a Wikipedia Project on the History of Science.

Chemistry Resources

Wikipedia:WikiProject Chemicals/Data is a collection of links and references that are useful for chemistry-related works. This includes free online chemical databases, publications, patents, computer programs, and various tools.

unit-conversion.info A good place to figure out what equals what.

General Chemistry Online Clear text and comprehensive coverage of general chemistry topics by Fred Senese, Dept. of Chemistry Frostburg State University

General Chemistry Demonstration at Purdue Video clips (and descriptions) of lecture demonstrations.

Chemistry Webercises Directory A large listing of chemistry resources maintained by Steven Murov, Emeritus Chemistry Professor Modesto Junior College.

MathMol MathMol (Mathematics and Molecules) is a good starting point for those interested in the field of molecular modeling.

ABC-Chemistry A directory of free full-text journals in chemistry, biochemistry and related subjects.

The Element Song A goofy little song about all of the elements.

Selected image

The 8 allotropes of carbon
The 8 allotropes of carbon
Allotrope is the ability of a chemical to exhibit a number of different and physically distinct forms in its pure elemental state. The element carbon displays many allotropic forms, 8 of which are displayed here. They are (a) diamond, (b) graphite, (c) lonsdaleite, (d) buckminsterfullerene, (e) C540, (f) C70, (g) amorphous carbon and (h) a single walled carbon nanotube.

Selected biography

Hermann Emil Fischer
Hermann Emil Fischer (1852-1919) was a German chemist, and recipient of the Nobel Prize for Chemistry in 1902. Many consider Fischer to be the most brilliant chemist who ever lived, because of his numerous contributions to science, especially chemistry and biochemistry. Among these is his discovery of phenylhydrazine. He also undertook vast studies on purines. This work showed that various substances such as adenine, xanthine, caffeine, uric acid, and guanine, all belonged to one homogeneous family, and could be derived from one another. He reasoned this to be due to their common origins from a parent molecule, a bicyclic nitrogenous structure into which the characteristic urea group entered. Fischer regarded this structure as hypothetical, and named it 'purine' in 1884. He synthesised it in 1898. He is also famed for his work on sugars.

Techniques used by chemists

Equipment used by chemists

Chemistry in society

Chemistry in industry

WikiProjects

Topics

Periodic Table

Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Hydrogen &
alkali metals
Alkaline earth metals Triels Tetrels Pnicto­gens Chal­co­gens Halo­gens Noble
gases
Period

1

Hydro­gen1H1.0080 He­lium2He4.0026
2 Lith­ium3Li6.94 Beryl­lium4Be9.0122 Boron5B10.81 Carbon6C12.011 Nitro­gen7N14.007 Oxy­gen8O15.999 Fluor­ine9F18.998 Neon10Ne20.180
3 So­dium11Na22.990 Magne­sium12Mg24.305 Alumin­ium13Al26.982 Sili­con14Si28.085 Phos­phorus15P30.974 Sulfur16S32.06 Chlor­ine17Cl35.45 Argon18Ar39.95
4 Potas­sium19K39.098 Cal­cium20Ca40.078 Scan­dium21Sc44.956 Tita­nium22Ti47.867 Vana­dium23V50.942 Chrom­ium24Cr51.996 Manga­nese25Mn54.938 Iron26Fe55.845 Cobalt27Co58.933 Nickel28Ni58.693 Copper29Cu63.546 Zinc30Zn65.38 Gallium31Ga69.723 Germa­nium32Ge72.630 Arsenic33As74.922 Sele­nium34Se78.971 Bromine35Br79.904 Kryp­ton36Kr83.798
5 Rubid­ium37Rb85.468 Stront­ium38Sr87.62 Yttrium39Y88.906 Zirco­nium40Zr91.224 Nio­bium41Nb92.906 Molyb­denum42Mo95.95 Tech­netium43Tc​[97] Ruthe­nium44Ru101.07 Rho­dium45Rh102.91 Pallad­ium46Pd106.42 Silver47Ag107.87 Cad­mium48Cd112.41 Indium49In114.82 Tin50Sn118.71 Anti­mony51Sb121.76 Tellur­ium52Te127.60 Iodine53I126.90 Xenon54Xe131.29
6 Cae­sium55Cs132.91 Ba­rium56Ba137.33 1 asterisk Lute­tium71Lu174.97 Haf­nium72Hf178.49 Tanta­lum73Ta180.95 Tung­sten74W183.84 Rhe­nium75Re186.21 Os­mium76Os190.23 Iridium77Ir192.22 Plat­inum78Pt195.08 Gold79Au196.97 Mer­cury80Hg200.59 Thallium81Tl204.38 Lead82Pb207.2 Bis­muth83Bi208.98 Polo­nium84Po​[209] Asta­tine85At​[210] Radon86Rn​[222]
7 Fran­cium87Fr​[223] Ra­dium88Ra​[226] 1 asterisk Lawren­cium103Lr​[266] Ruther­fordium104Rf​[267] Dub­nium105Db​[268] Sea­borgium106Sg​[269] Bohr­ium107Bh​[270] Has­sium108Hs​[271] Meit­nerium109Mt​[278] Darm­stadtium110Ds​[281] Roent­genium111Rg​[282] Coper­nicium112Cn​[285] Nihon­ium113Nh​[286] Flerov­ium114Fl​[289] Moscov­ium115Mc​[290] Liver­morium116Lv​[293] Tenness­ine117Ts​[294] Oga­nesson118Og​[294]
1 asterisk Lan­thanum57La138.91 Cerium58Ce140.12 Praseo­dymium59Pr140.91 Neo­dymium60Nd144.24 Prome­thium61Pm​[145] Sama­rium62Sm150.36 Europ­ium63Eu151.96 Gadolin­ium64Gd157.25 Ter­bium65Tb158.93 Dyspro­sium66Dy162.50 Hol­mium67Ho164.93 Erbium68Er167.26 Thulium69Tm168.93 Ytter­bium70Yb173.05  
1 asterisk Actin­ium89Ac​[227] Thor­ium90Th232.04 Protac­tinium91Pa231.04 Ura­nium92U238.03 Neptu­nium93Np​[237] Pluto­nium94Pu​[244] Ameri­cium95Am​[243] Curium96Cm​[247] Berkel­ium97Bk​[247] Califor­nium98Cf​[251] Einstei­nium99Es​[252] Fer­mium100Fm​[257] Mende­levium101Md​[258] Nobel­ium102No​[259]

Associated Wikimedia

The following Wikimedia Foundation sister projects provide more on this subject:

Sources

  1. ^ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–291. doi:10.1515/pac-2015-0305.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
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