In mathematics, a differentialdQ is said to be exact, as contrasted with an inexact differential, if the functionQ exists. It is always possible to calculate the differential dQ of a given function Q(x, y, z). However, if dQ is arbitrarily given, the function Q generally does not exist.
Overview
In one dimension, a differential
is always exact. In two dimensions, in order that a differential
be an exact differential in a simply-connected region R of the xy-plane, it is necessary and sufficient that between A and B there exists the relation:
In three dimensions, a differential
is an exact differential in a simply-connected region R of the xyz-coordinate system if between the functions A, B and C there exist the relations:
;;
These conditions, which are easy to generalize, arise from the independence of the order of differentiations in the calculation of the second derivatives. So, in order for a differential dQ, that is a function of four variables to be an exact differential, there are six conditions to satisfy.
In summary, when a differential dQ is exact:
the function Q exists;
, independent of the path followed.
In thermodynamics, when dQ is exact, the function Q is a state function of the system. The thermodynamic functions U, S, H, A and G are state functions. Generally, neither work nor heat is a state function. An exact differential is sometimes also called a 'total differential', or a 'full differential', or, in the study of differential geometry, it is termed an exact form.
Some useful equations derived from exact differentials in two dimensions
Suppose we have five state functions , and . Suppose that the state space is two dimensional and any of the five quantites are exact differentials. Then by the chain rule