Jump to content

Waste-to-energy

From Wikipedia, the free encyclopedia
(Redirected from Thermal recycling)

Spittelau incineration plant [de], with its distinct Hundertwasser facade, is providing combined heat and power in Vienna.

Waste-to-energy (WtE) or energy-from-waste (EfW) refers to a series of processes designed to convert waste materials into usable forms of energy, typically electricity or heat. As a form of energy recovery, WtE plays a crucial role in both waste management and sustainable energy production by reducing the volume of waste in landfills and providing an alternative energy source.

The most common method of WtE is direct combustion of waste to produce heat, which can then be used to generate electricity via steam turbines. This method is widely employed in many countries and offers a dual benefit: it disposes of waste while generating energy, making it an efficient process for both waste reduction and energy production.

In addition to combustion, other WtE technologies focus on converting waste into fuel sources. For example, gasification and pyrolysis are processes that thermochemically decompose organic materials in the absence of oxygen to produce syngas, a synthetic gas primarily composed of hydrogen, carbon monoxide, and small amounts of carbon dioxide. This syngas can be converted into methane, methanol, ethanol, or even synthetic fuels, which can be used in various industrial processes or as alternative fuels in transportation.

Furthermore, anaerobic digestion, a biological process, converts organic waste into biogas (mainly methane and carbon dioxide) through microbial action. This biogas can be harnessed for energy production or processed into biomethane, which can serve as a substitute for natural gas.

The WtE process contributes to circular economy principles by transforming waste products into valuable resources, reducing dependency on fossil fuels, and mitigating greenhouse gas emissions. However, challenges remain, particularly in ensuring that emissions from WtE plants, such as dioxins and furans, are properly managed to minimize environmental impact. Advanced pollution control technologies are essential to address these concerns and ensure WtE remains a viable, environmentally sound solution.

WtE technologies present a significant opportunity to manage waste sustainably while contributing to global energy demands. They represent an essential component of integrated waste management strategies and a shift toward renewable energy systems. As technology advances, WtE may play an increasingly critical role in both reducing landfill use and enhancing energy security.

History

[edit]

Methods

[edit]

Incineration

[edit]

Incineration, the combustion of organic material such as waste with energy recovery, is the most common WtE implementation. All new WtE plants in OECD countries incinerating waste (residual MSW, commercial, industrial or RDF) must meet strict emission standards, including those on nitrogen oxides (NOx), sulphur dioxide (SO2), heavy metals and dioxins.[6][7] Hence, modern incineration plants are vastly different from old types, some of which neither recovered energy nor materials. Modern incinerators reduce the volume of the original waste by 95-96 percent, depending upon composition and degree of recovery of materials such as metals from the ash for recycling.[3]

Incinerators may emit fine particulate, heavy metals, trace dioxin and acid gas, even though these emissions are relatively low[8] from modern incinerators. Other concerns include proper management of residues: toxic fly ash, which must be handled in hazardous waste disposal installation as well as incinerator bottom ash (IBA), which must be reused properly.[9]

Critics argue that incinerators destroy valuable resources and they may reduce incentives for recycling.[9] The question, however, is an open one, as European countries which recycle the most (up to 70%) also incinerate to avoid landfilling.[10]

Incinerators have electric efficiencies of 14-28%.[9] In order to avoid losing the rest of the energy, it can be used for e.g. district heating (cogeneration). The total efficiencies of cogeneration incinerators are typically higher than 80% (based on the lower heating value of the waste).

The method of incineration to convert municipal solid waste (MSW) is a relatively old method of WtE generation. Incineration generally entails burning waste (residual MSW, commercial, industrial and RDF) to boil water which powers steam generators that generate electric energy and heat to be used in homes, businesses, institutions and industries. One problem associated is the potential for pollutants to enter the atmosphere with the flue gases from the boiler. These pollutants can be acidic and in the 1980s were reported to cause environmental degradation by turning rain into acid rain. Modern incinerators incorporate carefully engineered primary and secondary burn chambers, and controlled burners designed to burn completely with the lowest possible emissions, eliminating, in some cases, the need for lime scrubbers and electro-static precipitators on smokestacks.

By passing the smoke through the basic lime scrubbers, any acids that might be in the smoke are neutralized which prevents the acid from reaching the atmosphere and hurting the environment. Many other devices, such as fabric filters, reactors, and catalysts destroy or capture other regulated pollutants.[11] According to the New York Times, modern incineration plants are so clean that "many times more dioxin is now released from home fireplaces and backyard barbecues than from incineration".[12] According to the German Environmental Ministry, "because of stringent regulations, waste incineration plants are no longer significant in terms of emissions of dioxins, dust, and heavy metals".[13]

Compared with other waste to energy technologies, incineration seems to be the most attractive due to its higher power production efficiency, lower investment costs, and lower emission rates. Additionally, incineration yields the highest amount of electricity with the highest capacity to lessen pile of wastes in landfills through direct combustion.[14]

Fuel from plastics

[edit]

One process that is used to convert plastic into fuel is pyrolysis, the thermal decomposition of materials at high temperatures in an inert atmosphere. It involves change of chemical composition and is mainly used for treatment of organic materials. In large scale production, plastic waste is ground and melted and then pyrolyzed. Catalytic converters help in the process. The vapours are condensed with oil or fuel and accumulated in settling tanks and filtered. Fuel is obtained after homogenation and can be used for automobiles and machinery. It is commonly termed as thermofuel or energy from plastic.[15]

A new process uses a two-part catalyst, cobalt and zeolite, to convert plastics into propane. It works on polyethylene and polypropylene and the propane yield is approximately 80%.[16]

Other

[edit]

There are a number of other new and emerging technologies that are able to produce energy from waste and other fuels without direct combustion. Many of these technologies have the potential to produce more electric power from the same amount of fuel than would be possible by direct combustion. This is mainly due to the separation of corrosive components (ash) from the converted fuel, thereby allowing higher combustion temperatures in e.g. boilers, gas turbines, internal combustion engines, fuel cells. Some advanced technologies are able to efficiently convert the energy in the feedstocks into liquid or gaseous fuels, using heat but in the absence of oxygen, without actual combustion, by using a combination of thermal technologies. Typically, they are cleaner, as the feedstock is separated prior to treatment to remove the unwanted components:

Pyrolysis Plant

Thermal treatment technologies include:

Landfill Gas Collection

Non-thermal technologies:

Global developments

[edit]
Waste-to-energy generating capacity in the United States
Waste-to-energy plants in the United States

During the 2001–2007 period, the waste-to-energy capacity increased by about four million metric tons per year.

Japan and China each built several plants based on direct smelting or on fluidized bed combustion of solid waste. In China there were about 434 waste-to-energy plants in early 2016. Japan is the largest user in thermal treatment of municipal solid waste in the world, with 40 million tons.

Some of the newest plants use stoker technology and others use the advanced oxygen enrichment technology. Several treatment plants exist worldwide using relatively novel processes such as direct smelting, the Ebara fluidization process and the Thermoselect JFE gasification and melting technology process.[18]

As of June 2014, Indonesia had a total of 93.5 MW installed capacity of waste-to-energy, with a pipeline of projects in different preparation phases together amounting to another 373MW of capacity.[19]

Biofuel Energy Corporation of Denver, Colorado, opened two new biofuel plants in Wood River, Nebraska, and Fairmont, Minnesota, in July 2008. These plants use distillation to make ethanol for use in motor vehicles and other engines. Both plants are currently reported to be working at over 90% capacity. Fulcrum BioEnergy, located in Pleasanton, California, is building a WtE plant near Reno, NV. The plant is scheduled to open in 2019 under the name of Sierra BioFuels plant. BioEnergy incorporated predicts that the plant will produce approximately 10.5 million gallons per year of ethanol from nearly 200,000 tons per year of MSW.[20]

Waste-to-energy technology includes fermentation, which can take biomass and create ethanol, using waste cellulosic or organic material.[17] In the fermentation process, the sugar in the waste is converted to carbon dioxide and alcohol, in the same general process that is used to make wine. Normally fermentation occurs with no air present.

Esterification can also be done using waste-to-energy technologies, and the result of this process is biodiesel. The cost-effectiveness of esterification will depend on the feedstock being used, and all the other relevant factors such as transportation distance, amount of oil present in the feedstock, and others.[21] Gasification and pyrolysis by now can reach gross thermal conversion efficiencies (fuel to gas) up to 75%, however, a complete combustion is superior in terms of fuel conversion efficiency.[5] Some pyrolysis processes need an outside heat source which may be supplied by the gasification process, making the combined process self-sustaining.

Carbon dioxide emissions

[edit]

In thermal WtE technologies, nearly all of the carbon content in the waste is emitted as carbon dioxide (CO2) to the atmosphere (when including final combustion of the products from pyrolysis and gasification; except when producing biochar for fertilizer). Municipal solid waste (MSW) contain approximately the same mass fraction of carbon as CO2 itself (27%), so treatment of 1 metric ton (1.1 short tons) of MSW produce approximately 1 metric ton (1.1 short tons) of CO2.

In the event that the waste was landfilled, 1 metric ton (1.1 short tons) of MSW would produce approximately 62 cubic metres (2,200 cu ft) methane via the anaerobic decomposition of the biodegradable part of the waste. This amount of methane has more than twice the global warming potential than the 1 metric ton (1.1 short tons) of CO2, which would have been produced by combustion. In some countries, large amounts of landfill gas are collected. However, there is still the global warming potential of the landfill gas being emitted to atmosphere. For example, in the US in 1999 landfill gas emission was approximately 32% higher than the amount of CO2 that would have been emitted by combustion.[22]

In addition, nearly all biodegradable waste is biomass. That is, it has biological origin. This material has been formed by plants using atmospheric CO2 typically within the last growing season. If these plants are regrown the CO2 emitted from their combustion will be taken out from the atmosphere once more.

Such considerations are the main reason why several countries administrate WtE of the biomass part of waste as renewable energy.[23] The rest—mainly plastics and other oil and gas derived products—is generally treated as non-renewables.

The CO2 emissions from plastic waste-to-energy systems are higher than those from current fossil fuel-based power systems per unit of power generated, even after considering the contribution of carbon capture and storage. Power generation using plastic waste will significantly increase by 2050. Carbon must be separated during energy recovery processes. Otherwise, the fight against global warming would fail due to plastic waste.[24]

Determination of the biomass fraction

[edit]

MSW to a large extent is of biological origin (biogenic), e.g. paper, cardboard, wood, cloth, food scraps. Typically half of the energy content in MSW is from biogenic material.[25] Consequently, this energy is often recognised as renewable energy according to the waste input.[26]

Several methods have been developed by the European CEN 343 working group to determine the biomass fraction of waste fuels, such as Refuse Derived Fuel/Solid Recovered Fuel. The initial two methods developed (CEN/TS 15440) were the manual sorting method and the selective dissolution method. A detailed systematic comparison of these two methods was published in 2010.[27] Since each method suffered from limitations in properly characterizing the biomass fraction, two alternative methods have been developed.

The first method uses the principles of radiocarbon dating. A technical review (CEN/TR 15591:2007) outlining the carbon 14 method was published in 2007. A technical standard of the carbon dating method (CEN/TS 15747:2008) is published in 2008.[needs update] In the United States, there is already an equivalent carbon 14 method under the standard method ASTM D6866.

The second method (so-called balance method) employs existing data on materials composition and operating conditions of the WtE plant and calculates the most probable result based on a mathematical-statistical model.[28] Currently the balance method is installed at three Austrian and eight Danish incinerators.

A comparison between both methods carried out at three full-scale incinerators in Switzerland showed that both methods came to the same results.[29]

Carbon 14 dating can determine with precision the biomass fraction of waste, and also determine the biomass calorific value. Determining the calorific value is important for green certificate programs such as the Renewable Obligation Certificate program in the United Kingdom. These programs award certificates based on the energy produced from biomass. Several research papers, including the one commissioned by the Renewable Energy Association in the UK, have been published that demonstrate how the carbon 14 result can be used to calculate the biomass calorific value. The UK gas and electricity markets authority, Ofgem, released a statement in 2011 accepting the use of Carbon 14 as a way to determine the biomass energy content of waste feedstock under their administration of the Renewables Obligation.[30] Their Fuel Measurement and Sampling (FMS) questionnaire describes the information they look for when considering such proposals.[31]

Physical location

[edit]

A 2019 report commissioned by the Global Alliance for Incinerator Alternatives (GAIA), done by the Tishman Environment and Design Center at The New School, found that 79% of the then 73 operating waste-to-energy facilities in the U.S. are located in low-income communities and/or "communities of color", because "of historic residential, racial segregation and expulsive zoning laws that allowed whiter, wealthier communities to exclude industrial uses and people of color from their boundaries."[32] In Chester, Pennsylvania, where a community group is actively opposing their local waste-to-energy facility, Sintana Vergara, an assistant professor in the Department of Environmental Resources Engineering at Humboldt State University in California, commented that community resistance is based on both the pollution and the fact that many of these facilities have been sited in communities without any community input, and without any benefits to the community.[33]

Notable examples

[edit]

According to a 2019 United Nations Environment Programme report, there are 589 WtE plants in Europe and 82 in the United States.[34]

The following are some examples of WtE plants.

Waste incineration WtE plants

[edit]

Liquid fuel producing plants

[edit]

A single plant is currently under construction:

Plasma gasification waste-to-energy plants

[edit]

The US Air Force once tested a Transportable Plasma Waste to Energy System (TPWES) facility (PyroGenesis technology) at Hurlburt Field, Florida.[39] The plant, which cost $7.4 million to construct,[40] was closed and sold at a government liquidation auction in May 2013, less than three years after its commissioning.[41][42] The opening bid was $25. The winning bid was sealed.

Besides large plants, domestic waste-to-energy incinerators also exist. For example, the Refuge de Sarenne has a domestic waste-to-energy plant. It is made by combining a wood-fired gasification boiler with a Stirling motor.[43][44]

Australia

[edit]

Renergi will scale up their system of converting waste organic materials into liquid fuels using a thermal treatment process in Collie, Western Australia. The system will process 1.5 tonnes of organic matter per hour. Annually the facility will divert 4000 tonnes of municipal waste from landfill and source an additional 8000 tonnes of organic waste from agricultural and forestry operations. Renergi’s patented “grinding pyrolysis” process aims to converts organic materials into biochar, bio-gases and bio-oil by applying heat in an environment with limited oxygen.[45]

Another project in the Rockingham Industrial Zone, roughly 45 kilometres south of Perth will see a 29 MW plant built with capacity to power 40,000 homes from an annual feedstock of 300,000 tonnes of municipal, industrial and commercial rubbish. As well as supplying electricity to the South West Interconnected System, 25 MW of the plant’s output has already been committed under a power purchase agreement.[46]

Africa

[edit]

The Reppie waste to energy plant in Ethiopia was the first such plant in Africa. The plant became operational in 2018.[47]

See also

[edit]

References

[edit]
  1. ^ Herbert, Lewis (2007). "Centenary History of Waste and Waste Managers in London and South East England" (PDF). Chartered Institution of Wastes Management.
  2. ^ "Energy Recovery - Basic Information". US EPA. 15 November 2016.
  3. ^ a b Thomas Astrup. Waste incineration – recovery of energy and material resources (PDF) (Report). Technical University of Denmark. p. 1. Archived from the original (PDF) on 2021-06-23.
  4. ^ Lapčík; et al. (December 2012). "Možnosti Energetického Využití Komunálního Odpadu". GeoScience Engineering.
  5. ^ a b The Viability of Advanced Thermal Treatment of MSW in the UK Archived 2013-05-08 at the Wayback Machine by Fichtner Consulting Engineers Ltd 2004
  6. ^ "Waste incineration". Europa. October 2011.
  7. ^ "DIRECTIVE 2000/76/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 December 2000 on the incineration of waste". European Union. 4 December 2000.
  8. ^ Emissionsfaktorer og emissionsopgørelse for decentral kraftvarme, Kortlægning af emissioner fra decentrale kraftvarmeværker, Ministry of the Environment of Denmark 2006 (in Danish)
  9. ^ a b c "Waste Gasification: Impacts on the Environment and Public Health" (PDF).
  10. ^ "Environment in the EU27 Landfill still accounted for nearly 40% of municipal waste treated in the EU27 in 2010". European Union. 27 March 2012.
  11. ^ Waste–to–Energy in Austria (PDF) (Report) (2nd ed.). Vienna: Austrian Ministry of Life. May 2010. Archived from the original (PDF) on 2013-06-27.
  12. ^ Rosenthal, Elisabeth (12 April 2010). "Europe Finds Clean Energy in Trash, but U.S. Lags". The New York Times.
  13. ^ "Waste incineration – A potential danger? Bidding farewell to dioxin spouting" (PDF). Federal Ministry for Environment, Nature Conservation and Nuclear Safety. September 2005. Archived from the original (PDF) on 2018-10-25. Retrieved 2013-04-16.
  14. ^ Agaton, Casper Boongaling; Guno, Charmaine Samala; Villanueva, Resy Ordona; Villanueva, Riza Ordona (1 October 2020). "Economic analysis of waste-to-energy investment in the Philippines: A real options approach". Applied Energy. 275. 115265. Bibcode:2020ApEn..27515265A. doi:10.1016/j.apenergy.2020.115265. ISSN 0306-2619.
  15. ^ "Fuel from Plastics | Seminar 2021". 2 January 2021 – via YouTube.
  16. ^ Crownhart, Casey (30 November 2022). "How chemists are tackling the plastics problem". MIT Technology Review. Retrieved 2023-02-25.
  17. ^ a b Fackler, Nick; Heijstra, Björn D.; Rasor, Blake J.; Brown, Hunter; Martin, Jacob; Ni, Zhuofu; Shebek, Kevin M.; Rosin, Rick R.; Simpson, Séan D.; Tyo, Keith E.; Giannone, Richard J.; Hettich, Robert L.; Tschaplinski, Timothy J.; Leang, Ching; Brown, Steven D.; Jewett, Michael C.; Köpke, Michael (7 June 2021). "Stepping on the Gas to a Circular Economy: Accelerating Development of Carbon-Negative Chemical Production from Gas Fermentation". Annual Review of Chemical and Biomolecular Engineering. 12 (1): 439–470. doi:10.1146/annurev-chembioeng-120120-021122. ISSN 1947-5438. OSTI 1807218. PMID 33872517. S2CID 233310092.
  18. ^ "Waste Council Attracts Experts Worldwide". Columbia Engineering, Columbia University. Archived from the original on 2017-12-25. Retrieved 2008-10-31.
  19. ^ "Waste to energy in Indonesia". The Carbon Trust. June 2014. Archived from the original on 2018-11-21. Retrieved 2014-07-22.
  20. ^ "Sierra BioFuels Plant". fulcrum-bioenergy.com. Fulcrum BioEnergy. Archived from the original on 2017-02-04.
  21. ^ "Cost Effective Waste to Energy Technologies – Updated Article With Extra Information". bionomicfuel.com. Retrieved 2015-02-28.
  22. ^ Themelis, Nickolas J. An overview of the global waste-to-energy industry Archived 2014-02-06 at the Wayback Machine, Waste Management World 2003
  23. ^ "Biomass & Bioenergy > Energy from Waste". Renewable Energy Association. Archived from the original on 2009-03-26.
  24. ^ Kwon, Serang; Kang, Jieun; Lee, Beomhui; Hong, Soonwook; Jeon, Yongseok; Bak, Moonsoo; Im, Seong-kyun (12 July 2023). "Nonviable carbon neutrality with plastic waste-to-energy". Energy & Environmental Science. 16 (7): 3074–3087. doi:10.1039/D3EE00969F. ISSN 1754-5706.
  25. ^ "More recycling raises average energy content of waste used to generate electricity". U.S. Energy Information Administration. September 2012.
  26. ^ "Directive 2009/28/EC on the promotion of the use of energy from renewable sources". European Union. 23 April 2009.
  27. ^ Séverin, Mélanie; Velis, Costas A.; Longhurst, Phil J.; Pollard, Simon J.T. (July 2010). "The biogenic content of process streams from mechanical–biological treatment plants producing solid recovered fuel. Do the manual sorting and selective dissolution determination methods correlate?". Waste Management. 30 (7): 1171–1182. Bibcode:2010WaMan..30.1171S. doi:10.1016/j.wasman.2010.01.012. hdl:1826/5695. PMID 20116991.
  28. ^ Fellner, J.; Cencic, O.; Rechberger, H. (2007). "A New Method to Determine the Ratio of Electricity Production from Fossil and Biogenic Sources in Waste-to-Energy Plants". Environmental Science & Technology. 41 (7): 2579–2586. Bibcode:2007EnST...41.2579F. doi:10.1021/es0617587. PMID 17438819.
  29. ^ Mohn, J.; Szidat, S.; Fellner, J.; Rechberger, H.; Quartier, R.; Buchmann, B.; Emmenegger, L. (2008). "Determination of biogenic and fossil CO2 emitted by waste incineration based on 14CO2 and mass balances". Bioresource Technology. 99 (14): 6471–6479. Bibcode:2008BiTec..99.6471M. doi:10.1016/j.biortech.2007.11.042. PMID 18164616.
  30. ^ "Fuelled stations and FMS" (PDF). ofgem.gov.uk. Retrieved 2015-02-28.
  31. ^ "Fuel Measurement and Sampling (FMS) Questionnaire: Carbon-14". ofgem.gov.uk. 30 March 2012. Retrieved 2015-02-28.
  32. ^ Li, Rina (23 May 2019). "Nearly 80% of US incinerators located in marginalized communities, report reveals". Waste Dive.
  33. ^ Cooper, Kenny (3 May 2021). "Chester residents raise environmental racism concerns over Covanta incinerator". WHYY. I do think that there are two issues here, though. So one is the fact that, of course, incineration is going to produce some air pollution, even with the highest control technologies, some pollution is going to be produced," Vergara said. "But I think the second issue … is public perception and acceptance of a technology like this. So in the United States, we have a very long history of siting dirty power plants and waste facilities in communities of color, in low-income communities, who are bearing the risks of these facilities without necessarily sharing in any of the benefits.
  34. ^ "Waste to Energy: Considerations for Informed Decision-making". www.unep.org. International Environmental Technology Centre. 4 June 2019. Retrieved 2022-05-23.
  35. ^ Energy-from-Waste facility in Lee County Archived 2013-08-12 at the Wayback Machine run as Covanta Lee, Inc.
  36. ^ Algonquin Power Energy from Waste Facility Archived 2012-03-01 at the Wayback Machine from the homepage of Algonquin Power
  37. ^ a b "Waste to Biofuels and Chemicals Facility; Turning Garbage Into Fuel". www.edmonton.ca. City of Edmonton. Archived from the original on 2020-04-11. Retrieved 2020-04-02.
  38. ^ "Facilities & Projects | Clean Technology Around the World". Enerkem. Retrieved 2020-04-02.
  39. ^ "AFSOC makes 'green' history while investing in future". US Air Force Special Operations Command. Archived from the original on 2011-05-09. Retrieved 2011-04-28..
  40. ^ "Pyrogenesis Perfecting Plasma". Biomass Magazine.
  41. ^ "PyroGenesis Plasma Gasification and Waste Incineration System". Government Liquidation. Archived from the original on 2018-03-08. Retrieved 2016-05-02.
  42. ^ "DoD to Auction off Gasification Equipment - Renewable Energy from Waste". Archived from the original on 2014-10-18. Retrieved 2016-05-02.
  43. ^ "Autonomie énergétique pour un refuge de montagne: panneaux solaires". Connaissance des Énergies. 5 July 2012. Retrieved 2015-02-28.
  44. ^ "Biomass Carbonization Plant". Kingtiger (Shanghai) Environmental Technology.
  45. ^ "Re-energising waste in south-west WA - ARENAWIRE". Australian Renewable Energy Agency. 28 January 2021. Retrieved 2021-01-29.
  46. ^ "Second waste-to-energy plant gets green light - ARENAWIRE". Australian Renewable Energy Agency. 22 January 2020. Retrieved 2021-01-29.
  47. ^ "Ethiopia's waste-to-energy plant is a first in Africa". www.unep.org. 24 November 2017. Retrieved 2024-11-12.

Further reading

[edit]
  • Field, Christopher B. "Emissions pathways, climate change, and impacts." PNAS 101.34 (2004): 12422–12427.
  • Sudarsan, K. G.; Anupama, Mary P. (October 2009). "The Relevance of Biofuels" (PDF). Current Science. 90 (6). Archived from the original (PDF) on 2015-09-24.
  • Tilman, David. "Environmental, economic, and energetic costs." PNAS 103.30 (2006): 11206–11210.
[edit]